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Synthesis of axially chiral gold complexes and their applications in asymmetric catalyses

Several novel chiral N-heterocyclic carbene and phosphine ligands were prepared from (S)-BINOL. Moreover, their ligated Au complexes were also successfully synthesized and characterized by X-ray crystal diffraction. A weak gold-π interaction between the Au atom and the aromatic ring in these gold co...

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Detalles Bibliográficos
Autores principales: Sun, Yin-wei, Xu, Qin, Shi, Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3817475/
https://www.ncbi.nlm.nih.gov/pubmed/24204435
http://dx.doi.org/10.3762/bjoc.9.261