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Regioselective carbon–carbon bond formation of 5,5,5-trifluoro-1-phenylpent-3-en-1-yne

The regioselective carbon–carbon bond formation was studied using 5,5,5-trifluoro-1-phenylpent-3-en-1-yne as a model substrate, and predominant acceptance of electrophiles β to a CF(3) group as well as a deuterium trap experiment of the lithiated species led to the conclusion that the obtained regio...

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Detalles Bibliográficos
Autores principales: Naka, Motoki, Kawasaki-Takasuka, Tomoko, Yamazaki, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3817480/
https://www.ncbi.nlm.nih.gov/pubmed/24204431
http://dx.doi.org/10.3762/bjoc.9.256