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Stereoselective synthesis of the C79–C97 fragment of symbiodinolide

Symbiodinolide is a polyol marine natural product with a molecular weight of 2860. Herein, a streamlined synthesis of the C79–C97 fragment of symbiodinolide is described. In the synthetic route, a spiroacetalization, a Julia–Kocienski olefination, and a Sharpless asymmetric dihydroxylation were util...

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Detalles Bibliográficos
Autores principales: Takamura, Hiroyoshi, Fujiwara, Takayuki, Kadota, Isao, Uemura, Daisuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3817580/
https://www.ncbi.nlm.nih.gov/pubmed/24204403
http://dx.doi.org/10.3762/bjoc.9.228