Nucleophilic ortho-Allylation of Pyrroles and Pyrazoles: An Accelerated Pummerer/Thio-Claisen Rearrangement Sequence

[Image: see text] Arylsulfinyl groups direct the metal-free, regiospecific, nucleophilic ortho-allylation of pyrroles and pyrazoles. Mechanistic studies support the intermediacy of allylsulfonium salts that undergo facile thio-Claisen rearrangement onto the heterocyclic ring, giving products of coup...

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Detalles Bibliográficos
Autores principales: Eberhart, Andrew J., Cicoira, Claudio, Procter, David J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3819180/
https://www.ncbi.nlm.nih.gov/pubmed/23855635
http://dx.doi.org/10.1021/ol401786d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3819180/
https://www.ncbi.nlm.nih.gov/pubmed/23855635
http://dx.doi.org/10.1021/ol401786d

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