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On the Silver Effect and the Formation of Chloride-Bridged Digold Complexes

[Image: see text] Abstraction of chloride anion from Au(I) complexes such as JohnPhosAuCl in noncoordinating solvents with 1 equiv of a silver salt, or even larger amounts, leads to the formation of chloride-bridged dinuclear gold(I) complexes, irrespective of the counteranion, which are substantial...

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Detalles Bibliográficos
Autores principales: Homs, Anna, Escofet, Imma, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3833279/
https://www.ncbi.nlm.nih.gov/pubmed/24195441
http://dx.doi.org/10.1021/ol402825v