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On the Silver Effect and the Formation of Chloride-Bridged Digold Complexes
[Image: see text] Abstraction of chloride anion from Au(I) complexes such as JohnPhosAuCl in noncoordinating solvents with 1 equiv of a silver salt, or even larger amounts, leads to the formation of chloride-bridged dinuclear gold(I) complexes, irrespective of the counteranion, which are substantial...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2013
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3833279/ https://www.ncbi.nlm.nih.gov/pubmed/24195441 http://dx.doi.org/10.1021/ol402825v |