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Conformational Properties of 1-Halogenated-1-Silacyclohexanes, C(5)H(10)SiHX (X = Cl, Br, I): Gas Electron Diffraction, Low-Temperature NMR, Temperature-Dependent Raman Spectroscopy, and Quantum-Chemical Calculations†
[Image: see text] The molecular structures of axial and equatorial conformers of cyclo-C(5)H(10)SiHX (X = Cl, Br, I) as well as the thermodynamic equilibrium between these species was investigated by means of gas electron diffraction, dynamic nuclear magnetic resonance, temperature-dependent Raman s...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3862406/ https://www.ncbi.nlm.nih.gov/pubmed/24353364 http://dx.doi.org/10.1021/om4005725 |