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Conformational Properties of 1-Halogenated-1-Silacyclohexanes, C(5)H(10)SiHX (X = Cl, Br, I): Gas Electron Diffraction, Low-Temperature NMR, Temperature-Dependent Raman Spectroscopy, and Quantum-Chemical Calculations†

[Image: see text] The molecular structures of axial and equatorial conformers of cyclo-C(5)H(10)SiHX (X = Cl, Br, I) as well as the thermodynamic equilibrium between these species was investigated by means of gas electron diffraction, dynamic nuclear magnetic resonance, temperature-dependent Raman s...

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Detalles Bibliográficos
Autores principales: Wallevik, Sunna Ó., Bjornsson, Ragnar, Kvaran, Ágúst, Jonsdottir, Sigridur, Arnason, Ingvar, Belyakov, Alexander V., Kern, Thomas, Hassler, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3862406/
https://www.ncbi.nlm.nih.gov/pubmed/24353364
http://dx.doi.org/10.1021/om4005725