One-pot cross-enyne metathesis (CEYM)–Diels–Alder reaction of gem-difluoropropargylic alkynes

Propargylic difluorides 1 were used as starting substrates in a combination of cross-enyne metathesis and Diels–Alder reactions. Thus, the reaction of 1 with ethylene in the presence of 2(nd) generation Hoveyda–Grubbs catalyst generates a diene moiety which in situ reacts with a wide variety of dien...

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Detalles Bibliográficos
Autores principales: Fustero, Santos, Bello, Paula, Miró, Javier, Sánchez-Roselló, María, Haufe, Günter, del Pozo, Carlos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869219/
https://www.ncbi.nlm.nih.gov/pubmed/24367434
http://dx.doi.org/10.3762/bjoc.9.305

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869219/
https://www.ncbi.nlm.nih.gov/pubmed/24367434
http://dx.doi.org/10.3762/bjoc.9.305

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