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One-pot cross-enyne metathesis (CEYM)–Diels–Alder reaction of gem-difluoropropargylic alkynes
Propargylic difluorides 1 were used as starting substrates in a combination of cross-enyne metathesis and Diels–Alder reactions. Thus, the reaction of 1 with ethylene in the presence of 2(nd) generation Hoveyda–Grubbs catalyst generates a diene moiety which in situ reacts with a wide variety of dien...
Autores principales: | Fustero, Santos, Bello, Paula, Miró, Javier, Sánchez-Roselló, María, Haufe, Günter, del Pozo, Carlos |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869219/ https://www.ncbi.nlm.nih.gov/pubmed/24367434 http://dx.doi.org/10.3762/bjoc.9.305 |
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