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Consecutive cross-coupling reactions of 2,2-difluoro-1-iodoethenyl tosylate with boronic acids: efficient synthesis of 1,1-diaryl-2,2-difluoroethenes

The cross-coupling reactions of 2,2-difluoro-1-iodoethenyl tosylate (2) with 2 equiv of boronic acids in the presence of catalytic amounts of Pd(OAc)(2) and Na(2)CO(3) afforded the mono-coupled products 3 and 5 in high yields. The use of 4 equiv of boronic acids in the presence of catalytic amount o...

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Detalles Bibliográficos
Autores principales: Kim, Ju Hee, Choi, Su Jeong, Jeong, In Howa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869221/
https://www.ncbi.nlm.nih.gov/pubmed/24367415
http://dx.doi.org/10.3762/bjoc.9.286