Reaction of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithiethane with N-vinyl compounds

The reaction of hexafluorothioacetone dimer (2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithiethane, 1) with vinylamides leads to the rapid formation of [2 + 2] cycloadducts: 4-amino-2,2-bis(trifluoromethyl)thietanes. The reaction proceeds in polar solvents (DMF, DMSO) in the absence of a catalyst at ele...

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Detalles Bibliográficos
Autores principales: Petrov, Viacheslav A, Marshall, Will
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869268/
https://www.ncbi.nlm.nih.gov/pubmed/24367424
http://dx.doi.org/10.3762/bjoc.9.295

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869268/
https://www.ncbi.nlm.nih.gov/pubmed/24367424
http://dx.doi.org/10.3762/bjoc.9.295

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