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Modulating NHC catalysis with fluorine

Fluorination often confers a range of advantages in modulating the conformation and reactivity of small molecule organocatalysts. By strategically introducing fluorine substituents, as part of a β-fluoroamine motif, in a triazolium pre-catalyst, it was possible to modulate the behaviour of the corre...

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Detalles Bibliográficos
Autores principales: Rey, Yannick P, Gilmour, Ryan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869272/
https://www.ncbi.nlm.nih.gov/pubmed/24367445
http://dx.doi.org/10.3762/bjoc.9.316