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Stereodivergent synthesis of jaspine B and its isomers using a carbohydrate-derived alkoxyallene as C(3)-building block
Herein we present the synthesis of the anhydrophytosphingosine jaspine B and three of its stereoisomers using a carbohydrate-derived alkoxyallene in order to obtain the products in enantiopure form. Key step of the reaction sequence is the addition of the lithiated alkoxyallene to pentadecanal, sett...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869275/ https://www.ncbi.nlm.nih.gov/pubmed/24367420 http://dx.doi.org/10.3762/bjoc.9.291 |