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Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide

The trifluoromethylation of aryl iodides catalyzed by copper(I) salt with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide and Zn dust was accomplished. The catalytic reactions proceeded under mild reaction conditions, providing the corresponding aromatic trifluoromethylated...

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Detalles Bibliográficos
Autores principales: Nakamura, Yuzo, Fujiu, Motohiro, Murase, Tatsuya, Itoh, Yoshimitsu, Serizawa, Hiroki, Aikawa, Kohsuke, Mikami, Koichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3869366/
https://www.ncbi.nlm.nih.gov/pubmed/24367406
http://dx.doi.org/10.3762/bjoc.9.277