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Tri­chlorido­{meth­yl[4-(methyl­imino)­pent-2-en-2-yl]aza­nido-κ(2) N,N′}hafnium(IV)

The title complex, [Hf(C(29)H(41)N(2))Cl(3)], was synthesized from HfCl(4) and HC[C(Me)N((i)Pr(2)C(6)H(3))](2)Li(Et(2)O) in toluene. The structure is isotypic with those of Ti(IV) and Zr(IV) complexes reported previously [Nikiforov et al. (2007 ▶). Dalton Trans. pp. 4149–4159; Kakaliou et al. (1999...

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Detalles Bibliográficos
Autores principales: Ikeda, Ken, Masuda, Hideki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884379/
https://www.ncbi.nlm.nih.gov/pubmed/24426999
http://dx.doi.org/10.1107/S1600536813022745