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(2,2′-Bipyridine)chlorido[diethyl (2,2′:6′,2′′-terpyridin-4-yl)phosphonate]ruthenium(II) hexafluoridophosphate acetonitrile/water solvate
The cationic complex in the title compound, [RuCl(C(10)H(8)N(2))(C(19)H(20)N(3)O(3)P)]PF(6)·0.83CH(3)CN·0.17H(2)O, is a water-oxidation precatalyst functionalized for TiO(2) attachment via terpyridine phosphonate. The The Ru(II) atom in the complex has a distorted octahedral geometry due to the re...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884400/ https://www.ncbi.nlm.nih.gov/pubmed/24427002 http://dx.doi.org/10.1107/S1600536813022940 |