Synthesis, characterization and initial evaluation of 5-nitro-1-(trifluoromethyl)-3H-1λ(3),2-benziodaoxol-3-one

The synthesis of 5-nitro-1-(trifluoromethyl)-3H-1λ(3),2-benziodaoxol-3-one (3), a hypervalent-iodine-based electrophilic trifluoromethylating reagent, is described. Whereas considerations based on cyclic voltammetry and X-ray structural properties would predict an inferior reactivity when compared t...

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Detalles Bibliográficos
Autores principales: Santschi, Nico, Sarott, Roman C, Otth, Elisabeth, Kissner, Reinhard, Togni, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3896278/
https://www.ncbi.nlm.nih.gov/pubmed/24454557
http://dx.doi.org/10.3762/bjoc.10.1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3896278/
https://www.ncbi.nlm.nih.gov/pubmed/24454557
http://dx.doi.org/10.3762/bjoc.10.1

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