Cargando…

Gold(I) Carbenes by Retro-Buchner Reaction: Generation and Fate

[Image: see text] The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-aryl-1,3,5-cycloheptatrienes is dependent on the constitution of the ortho substituent. Indenes and fluorenes are obtained by intramolecular reaction of highly electrophilic gold(I) car...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Yahui, McGonigal, Paul R., Herlé, Bart, Besora, Maria, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3898715/
https://www.ncbi.nlm.nih.gov/pubmed/24358986
http://dx.doi.org/10.1021/ja411626v