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Gold(I) Carbenes by Retro-Buchner Reaction: Generation and Fate
[Image: see text] The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-aryl-1,3,5-cycloheptatrienes is dependent on the constitution of the ortho substituent. Indenes and fluorenes are obtained by intramolecular reaction of highly electrophilic gold(I) car...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3898715/ https://www.ncbi.nlm.nih.gov/pubmed/24358986 http://dx.doi.org/10.1021/ja411626v |