Cargando…

Gold(I) Carbenes by Retro-Buchner Reaction: Generation and Fate

[Image: see text] The fate of the aryl gold(I) carbenes generated by retro-Buchner reaction of ortho-substituted 7-aryl-1,3,5-cycloheptatrienes is dependent on the constitution of the ortho substituent. Indenes and fluorenes are obtained by intramolecular reaction of highly electrophilic gold(I) car...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Yahui, McGonigal, Paul R., Herlé, Bart, Besora, Maria, Echavarren, Antonio M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2013
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3898715/ https://www.ncbi.nlm.nih.gov/pubmed/24358986 http://dx.doi.org/10.1021/ja411626v

Ejemplares similares

Stereoselective cis-Vinylcyclopropanation via a Gold(I)-Catalyzed Retro-Buchner Reaction under Mild Conditions
por: Herlé, Bart, et al.
Publicado: (2017)

Hydroacenes Made Easy by Gold(I) Catalysis
por: Dorel, Ruth, et al.
Publicado: (2016)

Gold Carbene or Carbenoid: Is There a Difference?
por: Wang, Yahui, et al.
Publicado: (2015)

Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates
por: Dorel, Ruth, et al.
Publicado: (2015)

Gold(I) as an Artificial Cyclase: Short Stereodivergent Syntheses of (−)-Epiglobulol and (−)-4β,7α- and (−)-4α,7α-Aromadendranediols**
por: Carreras, Javier, et al.
Publicado: (2014)

Rh(2)(ii)-catalyzed enantioselective intramolecular Büchner reaction and aromatic substitution of donor–donor carbenes
por: Zhu, Dong, et al.
Publicado: (2022)

Gold(I) Carbenoids: On‐Demand Access to Gold(I) Carbenes in Solution
por: Sarria Toro, Juan M., et al.
Publicado: (2017)

Direct Observation of Aryl Gold(I) Carbenes that Undergo Cyclopropanation, C−H Insertion, and Dimerization Reactions
por: García‐Morales, Cristina, et al.
Publicado: (2019)

The plays of Georg Büchner /
Publicado: (1971)

Assembly of Complex 1,4‐Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non‐Acceptor Carbenes
por: Armengol‐Relats, Helena, et al.
Publicado: (2020)

Georg Büchner's Wozzeck : Oper in 3 Akten (15 Szenen) Op. 7
por: Berg, Alban, 1885-1935
Publicado: (1931)

Georg Büchner, innovador del teatro occidental /
por: Wagner y Mesa, M. Aimée
Publicado: (2008)

Georg Büchner: Innovador del teatro occidental
por: Wagner y Mesa, M. AimÃ©e
Publicado: (2019)

On the Structure of Intermediates in Enyne Gold(I)‐Catalyzed Cyclizations: Formation of trans‐Fused Bicyclo[5.1.0]octanes as a Case Study
por: Escofet, Imma, et al.
Publicado: (2020)

Highly Efficient MOF-Driven Silver Subnanometer Clusters for the Catalytic Buchner Ring Expansion Reaction
por: Tiburcio, Estefanía, et al.
Publicado: (2022)

Concise Total Synthesis of Lundurines A–C Enabled by Gold Catalysis and a Homodienyl Retro-Ene/Ene Isomerization
por: Kirillova, Mariia S., et al.
Publicado: (2016)

α,β‐Unsaturated Gold(I) Carbenes by Tandem Cyclization and 1,5‐Alkoxy Migration of 1,6‐Enynes: Mechanisms and Applications
por: Calleja, Pilar, et al.
Publicado: (2016)

La naturaleza en la obra de Georg Büchner
por: Modern, Rodolf
Publicado: (1968)

Gold(i)-catalyzed cycloisomerization of vinylidenecyclopropane-enes via carbene or non-carbene processes
por: Li, De-Yao, et al.
Publicado: (2015)

Gold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenes
por: Romanov, Alexander S., et al.
Publicado: (2015)

A bonding model for gold(I) carbene complexes
por: Benitez, Diego, et al.
Publicado: (2009)

Enantioselective Cyclopropanation Catalyzed by Gold(I)-Carbene Complexes
por: Szabo, Zita, et al.
Publicado: (2022)

Franz Büchners Hypoxieforschung aus der Kriegszeit und der Nobelpreis
por: Malik, Elisa, et al.
Publicado: (2022)

N-Heterocyclic Carbene Gold(I) Complexes: Mechanism of the Ligand Scrambling Reaction and Their Oxidation to Gold(III) in Aqueous Solutions
por: Goetzfried, Sina K., et al.
Publicado: (2020)

Small Gold(I) and Gold(I)–Silver(I) Clusters by C−Si Auration
por: Pei, Xiao‐Li, et al.
Publicado: (2020)

Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis**
por: Wang, Yahui, et al.
Publicado: (2014)

Intriguing mechanistic labyrinths in gold(i) catalysis
por: Obradors, Carla, et al.
Publicado: (2014)

Reality is broken: why games make us better and how they can change the world
por: McGonigal, Jane
Publicado: (2011)

¿Por qué los videojuegos pueden mejorar tu vida y cambiar el mundo? : Un encuentro entre el mundo virtual y el real en el que las personas salen favorecidas
por: McGonigal, Jane
Publicado: (2013)

Aspirin for Frail Elderly Stroke Patients?
por: McGonigal, Gerard
Publicado: (1996)

Two Copper-Carbenes from One Diazo Compound
por: Álvarez, María, et al.
Publicado: (2021)

Ionization of gold (γ-methoxy)vinyl complexes generates reactive gold vinyl carbene complexes
por: Kim, Nana, et al.
Publicado: (2019)

Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity
por: Dorel, Ruth, et al.
Publicado: (2015)

Dataset of polyoxometalate-assisted N-heterocyclic carbene gold(I) complexes
por: Nomiya, Kenji, et al.
Publicado: (2019)

Gold(I) α‐Trifluoromethyl Carbenes: Synthesis, Characterization and Reactivity Studies
por: Rigoulet, Mathilde, et al.
Publicado: (2022)

Multi C−H Functionalization Reactions of Carbazole Heterocycles via Gold‐Catalyzed Carbene Transfer Reactions
por: Jana, Sripati, et al.
Publicado: (2021)

Cyclobutene vs 1,3-Diene Formation in the Gold-Catalyzed Reaction of Alkynes with Alkenes: The Complete Mechanistic Picture
por: de Orbe, M. Elena, et al.
Publicado: (2017)

Hydrogen-Bonded Matched Ion Pair Gold(I) Catalysis
por: Martí, Àlex, et al.
Publicado: (2023)

Ready Access to the Echinopines Skeleton via Gold(I)-Catalyzed Alkoxycyclizations of Enynes
por: Dorel, Ruth, et al.
Publicado: (2016)

Atom-economic generation of gold carbenes: gold-catalyzed formal [3+2] cycloaddition between ynamides and isoxazoles
por: Zhou, Ai-Hua, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_2fb91q9legapcb997qf01q6kdk