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Stereodivergent Synthesis of Chiral Fullerenes by [3 + 2] Cycloadditions to C(60)
[Image: see text] A wide range of new dipoles and catalysts have been used in 1,3-dipolar cycloadditions of N-metalated azomethine ylides onto C(60) yielding a full stereodivergent synthesis of pyrrolidino[60]fullerenes with complete diastereoselectivities and very high enantioselectivities. The use...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914395/ https://www.ncbi.nlm.nih.gov/pubmed/24359021 http://dx.doi.org/10.1021/ja410408c |