Cargando…

Stereodivergent Synthesis of Chiral Fullerenes by [3 + 2] Cycloadditions to C(60)

[Image: see text] A wide range of new dipoles and catalysts have been used in 1,3-dipolar cycloadditions of N-metalated azomethine ylides onto C(60) yielding a full stereodivergent synthesis of pyrrolidino[60]fullerenes with complete diastereoselectivities and very high enantioselectivities. The use...

Descripción completa

Detalles Bibliográficos
Autores principales:	Maroto, Enrique E., Filippone, Salvatore, Suárez, Margarita, Martínez-Álvarez, Roberto, de Cózar, Abel, Cossío, Fernando P., Martín, Nazario
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2013
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914395/ https://www.ncbi.nlm.nih.gov/pubmed/24359021 http://dx.doi.org/10.1021/ja410408c

Ejemplares similares

Enantioselective Cycloaddition of Münchnones onto [60]Fullerene: Organocatalysis versus Metal Catalysis
por: Marco-Martínez, Juan, et al.
Publicado: (2014)

On the regioselectivity of the Diels–Alder cycloaddition to C(60) in high spin states
por: El Bakouri, Ouissam, et al.
Publicado: (2018)

Ligand-dependent, palladium-catalyzed stereodivergent synthesis of chiral tetrahydroquinolines
por: Wang, Yue, et al.
Publicado: (2022)

Synthetic scope and DFT analysis of the chiral binap–gold(I) complex-catalyzed 1,3-dipolar cycloaddition of azlactones with alkenes
por: Martín-Rodríguez, María, et al.
Publicado: (2013)

Stereodivergent synthesis of chiral succinimides via Rh-catalyzed asymmetric transfer hydrogenation
por: Wang, Fangyuan, et al.
Publicado: (2022)

[2 + 1] Cycloaddition reactions of fullerene C(60) based on diazo compounds
por: Biglova, Yuliya N
Publicado: (2021)

Stereodivergent Chirality Transfer by Noncovalent Control of Disulfide Bonds
por: Zhang, Qi, et al.
Publicado: (2022)

Chiral gold(I) vs chiral silver complexes as catalysts for the enantioselective synthesis of the second generation GSK-hepatitis C virus inhibitor
por: Martín-Rodríguez, María, et al.
Publicado: (2011)

Chiral phosphoric acid-catalyzed stereodivergent synthesis of trisubstituted allenes and computational mechanistic studies
por: Wang, Jiawen, et al.
Publicado: (2020)

Morphological characterization of fullerene–androsterone conjugates
por: Ruiz, Alberto, et al.
Publicado: (2014)

Synthesis of [60]Fullerene Hybrids Endowed with Steroids and Monosaccharides: Theoretical Underpinning as Promising anti‐SARS‐CoV‐2 Agents
por: Lemos, Reinier, et al.
Publicado: (2023)

Growth of Fullerene Fragments Using the Diels-Alder Cycloaddition Reaction: First Step towards a C(60) Synthesis by Dimerization
por: Mojica, Martha, et al.
Publicado: (2013)

A Stereodivergent Approach to the Synthesis of gem‐Diborylcyclopropanes
por: Hanania, Nicole, et al.
Publicado: (2022)

Chiral aldehyde-nickel dual catalysis enables asymmetric α−propargylation of amino acids and stereodivergent synthesis of NP25302
por: Zhu, Fang, et al.
Publicado: (2022)

Hexakis-adducts of [60]fullerene as molecular scaffolds of polynuclear spin-crossover molecules
por: Palacios-Corella, Mario, et al.
Publicado: (2020)

Selective formation of dihydrofuran fused [60] fullerene derivatives by TEMPO mediated [3 + 2] cycloaddition of medium chain β-keto esters to C(60)
por: Jakšić, Jovana, et al.
Publicado: (2021)

Copper-catalyzed enantioselective stereodivergent synthesis of amino alcohols
por: Shi, Shi-Liang, et al.
Publicado: (2016)

Catalyst-Controlled Stereodivergent Synthesis of Atropisomeric Multiaxis Systems
por: Lotter, Dominik, et al.
Publicado: (2018)

Enhanced Thermoelectricity in Metal–[60]Fullerene–Graphene Molecular Junctions
por: Svatek, Simon A., et al.
Publicado: (2023)

Highly efficient synthesis of [60]fullerene oxides by plasma jet
por: Jiang, Sheng-Peng, et al.
Publicado: (2017)

A 3D Peptide/[60]Fullerene Hybrid for Multivalent Recognition
por: Gallego, Iván, et al.
Publicado: (2022)

First chemoenzymatic stereodivergent synthesis of both enantiomers of promethazine and ethopropazine
por: Borowiecki, Paweł, et al.
Publicado: (2014)

Stereodivergent synthesis of vicinal quaternary-quaternary stereocenters and bioactive hyperolactones
por: Zheng, Haifeng, et al.
Publicado: (2018)

Stereodivergent Synthesis of Camphor-Derived Diamines and Their Application as Thiourea Organocatalysts
por: Ričko, Sebastijan, et al.
Publicado: (2020)

Asymmetric Synthesis of Axially Chiral Molecules via Organocatalytic Cycloaddition and Cyclization Reactions
por: Cai, Wei-Yun, et al.
Publicado: (2023)

Evolution of a Unified, Stereodivergent Approach to the Synthesis of Communesin F and Perophoramidine
por: Han, Seo-Jung, et al.
Publicado: (2014)

Nickel‐Catalyzed Stereodivergent Synthesis of E‐ and Z‐Alkenes by Hydrogenation of Alkynes
por: Murugesan, Kathiravan, et al.
Publicado: (2019)

Stereodivergent synthesis of β-iodoenol carbamates with CO(2)via photocatalysis
por: Wang, Lu, et al.
Publicado: (2021)

Total synthesis of squafosacin F: stereodivergent approach to mono-tetrahydrofuran acetogenins
por: Ota, Koichiro, et al.
Publicado: (2019)

Stereodivergent Olefination of Enantioenriched Boronic Esters
por: Armstrong, Roly J., et al.
Publicado: (2016)

Protocol for stereodivergent asymmetric hydrogenation of quinoxalines
por: Wang, Mingyang, et al.
Publicado: (2023)

Regioselective and Stereodivergent Synthesis of Enantiomerically Pure Vic-Diamines from Chiral β-Amino Alcohols with 2-Pyridyl and 6-(2,2′-Bipyridyl) Moieties †
por: Wosińska-Hrydczuk, Marzena, et al.
Publicado: (2020)

Divergent synthesis of chiral cyclic azides via asymmetric cycloaddition reactions of vinyl azides
por: Thirupathi, Nuligonda, et al.
Publicado: (2019)

A retro Baeyer–Villiger reaction: electrochemical reduction of [60]fullerene-fused lactones to [60]fullerene-fused ketones
por: Niu, Chuang, et al.
Publicado: (2019)

Synthesis and Stability of Actinium-225 Endohedral Fullerenes, (225)Ac@C(60)
por: Mwakisege, Jofa Gideon, et al.
Publicado: (2020)

Synthesis and Electrochemistry of New Furylpyrazolino[60]fullerene Derivatives by Efficient Microwave Radiation
por: Al-Matar, Hamad M., et al.
Publicado: (2019)

Synthesis of an Azide- and Tetrazine-Functionalized [60]Fullerene and Its Controlled Decoration with Biomolecules
por: Gulumkar, Vijay, et al.
Publicado: (2021)

Synthesis of Site-Specific Antibody–[60]Fullerene–Oligonucleotide Conjugates for Cellular Targeting
por: Äärelä, Antti, et al.
Publicado: (2023)

Efficient and stereodivergent synthesis of unsaturated acyclic fragments bearing contiguous stereogenic elements
por: Bruffaerts, Jeffrey, et al.
Publicado: (2018)

Stereodivergent synthesis via iridium-catalyzed asymmetric double allylic alkylation of cyanoacetate
por: Shen, Chong, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_bgiug7gatrb31ocojgteq553to