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Hydrogen induced redox mechanism in amorphous carbon resistive random access memory

We investigated the bipolar resistive switching characteristics of the resistive random access memory (RRAM) device with amorphous carbon layer. Applying a forming voltage, the amorphous carbon layer was carbonized to form a conjugation double bond conductive filament. We proposed a hydrogen redox m...

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Autores principales: Chen, Yi-Jiun, Chen, Hsin-Lu, Young, Tai-Fa, Chang, Ting-Chang, Tsai, Tsung-Ming, Chang, Kuan-Chang, Zhang, Rui, Chen, Kai-Huang, Lou, Jen-Chung, Chu, Tian-Jian, Chen, Jung-Hui, Bao, Ding-Hua, Sze, Simon M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3922695/
https://www.ncbi.nlm.nih.gov/pubmed/24475979
http://dx.doi.org/10.1186/1556-276X-9-52
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author Chen, Yi-Jiun
Chen, Hsin-Lu
Young, Tai-Fa
Chang, Ting-Chang
Tsai, Tsung-Ming
Chang, Kuan-Chang
Zhang, Rui
Chen, Kai-Huang
Lou, Jen-Chung
Chu, Tian-Jian
Chen, Jung-Hui
Bao, Ding-Hua
Sze, Simon M
author_facet Chen, Yi-Jiun
Chen, Hsin-Lu
Young, Tai-Fa
Chang, Ting-Chang
Tsai, Tsung-Ming
Chang, Kuan-Chang
Zhang, Rui
Chen, Kai-Huang
Lou, Jen-Chung
Chu, Tian-Jian
Chen, Jung-Hui
Bao, Ding-Hua
Sze, Simon M
author_sort Chen, Yi-Jiun
collection PubMed
description We investigated the bipolar resistive switching characteristics of the resistive random access memory (RRAM) device with amorphous carbon layer. Applying a forming voltage, the amorphous carbon layer was carbonized to form a conjugation double bond conductive filament. We proposed a hydrogen redox model to clarify the resistive switch mechanism of high/low resistance states (HRS/LRS) in carbon RRAM. The electrical conduction mechanism of LRS is attributed to conductive sp(2) carbon filament with conjugation double bonds by dehydrogenation, while the electrical conduction of HRS resulted from the formation of insulating sp(3)-type carbon filament through hydrogenation process.
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spelling pubmed-39226952014-02-20 Hydrogen induced redox mechanism in amorphous carbon resistive random access memory Chen, Yi-Jiun Chen, Hsin-Lu Young, Tai-Fa Chang, Ting-Chang Tsai, Tsung-Ming Chang, Kuan-Chang Zhang, Rui Chen, Kai-Huang Lou, Jen-Chung Chu, Tian-Jian Chen, Jung-Hui Bao, Ding-Hua Sze, Simon M Nanoscale Res Lett Nano Express We investigated the bipolar resistive switching characteristics of the resistive random access memory (RRAM) device with amorphous carbon layer. Applying a forming voltage, the amorphous carbon layer was carbonized to form a conjugation double bond conductive filament. We proposed a hydrogen redox model to clarify the resistive switch mechanism of high/low resistance states (HRS/LRS) in carbon RRAM. The electrical conduction mechanism of LRS is attributed to conductive sp(2) carbon filament with conjugation double bonds by dehydrogenation, while the electrical conduction of HRS resulted from the formation of insulating sp(3)-type carbon filament through hydrogenation process. Springer 2014-01-29 /pmc/articles/PMC3922695/ /pubmed/24475979 http://dx.doi.org/10.1186/1556-276X-9-52 Text en Copyright © 2014 Chen et al.; licensee Springer. http://creativecommons.org/licenses/by/2.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.
spellingShingle Nano Express
Chen, Yi-Jiun
Chen, Hsin-Lu
Young, Tai-Fa
Chang, Ting-Chang
Tsai, Tsung-Ming
Chang, Kuan-Chang
Zhang, Rui
Chen, Kai-Huang
Lou, Jen-Chung
Chu, Tian-Jian
Chen, Jung-Hui
Bao, Ding-Hua
Sze, Simon M
Hydrogen induced redox mechanism in amorphous carbon resistive random access memory
title Hydrogen induced redox mechanism in amorphous carbon resistive random access memory
title_full Hydrogen induced redox mechanism in amorphous carbon resistive random access memory
title_fullStr Hydrogen induced redox mechanism in amorphous carbon resistive random access memory
title_full_unstemmed Hydrogen induced redox mechanism in amorphous carbon resistive random access memory
title_short Hydrogen induced redox mechanism in amorphous carbon resistive random access memory
title_sort hydrogen induced redox mechanism in amorphous carbon resistive random access memory
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3922695/
https://www.ncbi.nlm.nih.gov/pubmed/24475979
http://dx.doi.org/10.1186/1556-276X-9-52
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