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Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction
[Image: see text] Irradiation of CpRh(PMe(3))(C(2)H(4)) (1; Cp = η(5)-C(5)H(5)) in the presence of pentafluoropyridine in hexane solution at low temperature yields an isolable η(2)-C,C-coordinated pentafluoropyridine complex, CpRh(PMe(3))(η(2)-C,C-C(5)NF(4)) (2). The molecular structure of 2 was det...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2013
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3929166/ https://www.ncbi.nlm.nih.gov/pubmed/24563575 http://dx.doi.org/10.1021/om400552r |