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Palladium-Catalyzed Acetylation of Arenes

[Image: see text] A simple method for the preparation of aryl methyl ketones is reported. The transformation involves the Pd-catalyzed coupling of an acyl anion equivalent, acetyltrimethylsilane, with aryl bromides to afford the corresponding acetylated arenes in synthetically useful yields. The met...

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Detalles Bibliográficos
Autores principales: Ramgren, Stephen D., Garg, Neil K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3937967/
https://www.ncbi.nlm.nih.gov/pubmed/24405108
http://dx.doi.org/10.1021/ol403570z