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Synthesis of the B-seco limonoid core scaffold

Synthetic investigations towards the structurally complex and highly decorated framework of B-seco limonoid natural products by means of a [3,3]-sigmatropic rearrangement are described. Detailed model studies reveal, that an Ireland–Claisen rearrangement can be employed to construct the central C9–C...

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Detalles Bibliográficos
Autores principales: Bruss, Hanna, Schuster, Hannah, Martinez, Rémi, Kaiser, Markus, Antonchick, Andrey P, Waldmann, Herbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3943702/
https://www.ncbi.nlm.nih.gov/pubmed/24605139
http://dx.doi.org/10.3762/bjoc.10.15