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New hydrogen-bonding organocatalysts: Chiral cyclophosphazanes and phosphorus amides as catalysts for asymmetric Michael additions

Ten novel hydrogen-bonding catalysts based on open-chain P(V)-amides of BINOL and chinchona alkaloids as well as three catalysts based on rigid cis-P(V)-cyclodiphosphazane amides of N(1),N(1)-dimethylcyclohexane-1,2-diamine have been developed. Employed in the asymmetric Michael addition of 2-hydrox...

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Detalles Bibliográficos
Autores principales: Klare, Helge, Neudörfl, Jörg M, Goldfuss, Bernd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3944119/
https://www.ncbi.nlm.nih.gov/pubmed/24605142
http://dx.doi.org/10.3762/bjoc.10.18