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New hydrogen-bonding organocatalysts: Chiral cyclophosphazanes and phosphorus amides as catalysts for asymmetric Michael additions
Ten novel hydrogen-bonding catalysts based on open-chain P(V)-amides of BINOL and chinchona alkaloids as well as three catalysts based on rigid cis-P(V)-cyclodiphosphazane amides of N(1),N(1)-dimethylcyclohexane-1,2-diamine have been developed. Employed in the asymmetric Michael addition of 2-hydrox...
Autores principales: | Klare, Helge, Neudörfl, Jörg M, Goldfuss, Bernd |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3944119/ https://www.ncbi.nlm.nih.gov/pubmed/24605142 http://dx.doi.org/10.3762/bjoc.10.18 |
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