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Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol

[Image: see text] Few methods permit the hydrogenation of alkenes to a thermodynamically favored configuration when steric effects dictate the alternative trajectory of hydrogen delivery. Dissolving metal reduction achieves this control, but with extremely low functional group tolerance. Here we dem...

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Detalles Bibliográficos
Autores principales: Iwasaki, Kotaro, Wan, Kanny K., Oppedisano, Alberto, Crossley, Steven W. M., Shenvi, Ryan A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3951266/
https://www.ncbi.nlm.nih.gov/pubmed/24428640
http://dx.doi.org/10.1021/ja412342g