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Hydrophobic hydration of poly-N-isopropyl acrylamide: a matter of the mean energetic state of water

The enthalpically favoured hydration of hydrophobic entities, termed hydrophobic hydration, impacts the phase behaviour of numerous amphiphiles in water. Here, we show experimental evidence that hydrophobic hydration is strongly determined by the mean energetics of the aqueous medium. We investigate...

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Detalles Bibliográficos
Autores principales: Bischofberger, I., Calzolari, D. C. E., De Los Rios, P., Jelezarov, I., Trappe, V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3953744/
https://www.ncbi.nlm.nih.gov/pubmed/24625553
http://dx.doi.org/10.1038/srep04377