Cargando…

Hydrophobic hydration of poly-N-isopropyl acrylamide: a matter of the mean energetic state of water

The enthalpically favoured hydration of hydrophobic entities, termed hydrophobic hydration, impacts the phase behaviour of numerous amphiphiles in water. Here, we show experimental evidence that hydrophobic hydration is strongly determined by the mean energetics of the aqueous medium. We investigate...

Descripción completa

Detalles Bibliográficos
Autores principales:	Bischofberger, I., Calzolari, D. C. E., De Los Rios, P., Jelezarov, I., Trappe, V.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group 2014
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3953744/ https://www.ncbi.nlm.nih.gov/pubmed/24625553 http://dx.doi.org/10.1038/srep04377

Ejemplares similares

New aspects in the phase behaviour of poly-N-isopropyl acrylamide: systematic temperature dependent shrinking of PNiPAM assemblies well beyond the LCST
por: Bischofberger, Irmgard, et al.
Publicado: (2015)

Assessment of cytotoxicity of (N-isopropyl acrylamide) and Poly(N-isopropyl acrylamide)-coated surfaces
por: Cooperstein, Marta A, et al.
Publicado: (2013)

The Role of Backbone Hydration of Poly(N-isopropyl acrylamide) Across the Volume Phase Transition Compared to its Monomer
por: Futscher, Moritz H., et al.
Publicado: (2017)

Branched amphotericin functional poly(N-isopropyl acrylamide): an antifungal polymer
por: Swift, Thomas, et al.
Publicado: (2021)

Surface hydrolysis-mediated PEGylation of poly(N-isopropyl acrylamide) based nanogels
por: Peters, Jonathan T., et al.
Publicado: (2017)

Tuning the Size of Thermoresponsive Poly(N-Isopropyl Acrylamide) Grafted Silica Microgels
por: Nun, Nils, et al.
Publicado: (2017)

Stimuli-Responsive Langmuir Films Composed of Nanoparticles Decorated with Poly(N-isopropyl acrylamide) (PNIPAM) at the Air/Water Interface
por: Zbonikowski, Rafał, et al.
Publicado: (2023)

Development of thermo-responsive polycaprolactone macrocarriers conjugated with Poly(N-isopropyl acrylamide) for cell culture
por: Nguyen, Linh T. B., et al.
Publicado: (2019)

Reversible Self-Assembly of Backbone-Thermoresponsive Long Chain Hyperbranched Poly(N-Isopropyl Acrylamide)
por: Liu, Ting-Ting, et al.
Publicado: (2016)

Analysis using size exclusion chromatography of poly(N-isopropyl acrylamide) using methanol as an eluent
por: Swift, Thomas, et al.
Publicado: (2017)

Evaluation of ligand modified poly (N-Isopropyl acrylamide) hydrogel for etiological diagnosis of corneal infection
por: Shivshetty, Nagaveni, et al.
Publicado: (2022)

The Influence of Anionic Initiator on the Selected Properties of Poly-N-Isopropyl Acrylamide Evaluated for Controlled Drug Delivery
por: Gola, Agnieszka, et al.
Publicado: (2016)

RAFT Emulsion Polymerization of Styrene Using a Poly((N,N-dimethyl acrylamide)-co-(N-isopropyl acrylamide)) mCTA: Synthesis and Thermosensitivity
por: Nieswandt, Katharina, et al.
Publicado: (2021)

Aggregation-Induced Expansion of Poly-(N-isopropyl acrylamide) Solutions Observed Directly by the Transient Grating Imaging Technique
por: Kato, Daiki, et al.
Publicado: (2018)

Wrapping Up Hydrophobic Hydration: Locality Matters
por: Conti Nibali, V., et al.
Publicado: (2020)

Poly(N-Isopropyl-Acrylamide)/Poly(γ-Glutamic Acid) Thermo-Sensitive Hydrogels Loaded with Superoxide Dismutase for Wound Dressing Application
por: Dong, Yunsheng, et al.
Publicado: (2020)

Improved Dimensional Stability and Mold Resistance of Bamboo via In Situ Growth of Poly(Hydroxyethyl Methacrylate-N-Isopropyl Acrylamide)
por: Liu, Tingsong, et al.
Publicado: (2020)

Smart Hydrogels: Preparation, Characterization, and Determination of Transition Points of Crosslinked N-Isopropyl Acrylamide/Acrylamide/Carboxylic Acids Polymers
por: Işıkver, Yasemin, et al.
Publicado: (2021)

Anomalous Release Kinetics of Prodigiosin from Poly-N-Isopropyl-Acrylamid based Hydrogels for The Treatment of Triple Negative Breast Cancer
por: Danyuo, Y., et al.
Publicado: (2019)

Construction and Swelling Properties of Thermosensitive N-isopropyl Acrylamide Microspheres With Controllable Size
por: Wang, Chen, et al.
Publicado: (2019)

Biocatalytically active microgels by precipitation polymerization of N-isopropyl acrylamide in the presence of an enzyme
por: Reinicke, Stefan, et al.
Publicado: (2019)

Reversal of the Temperature Dependence of Hydrophobic Hydration in Supercooled Water
por: Ashbaugh, Henry S.
Publicado: (2021)

Highly-branched poly(N-isopropyl acrylamide) functionalised with pendant Nile red and chain end vancomycin for the detection of Gram-positive bacteria
por: Swift, Thomas, et al.
Publicado: (2019)

Optimizing the alignment of thermoresponsive poly(N-isopropyl acrylamide) electrospun nanofibers for tissue engineering applications: A factorial design of experiments approach
por: Young, Rachel E., et al.
Publicado: (2019)

Temperature/pH-Responsive Carboxymethyl Cellulose/Poly (N-isopropyl acrylamide) Interpenetrating Polymer Network Aerogels for Drug Delivery Systems
por: Liu, Zhongming, et al.
Publicado: (2022)

Feasibility evaluation of N-Isopropyl Acrylamide 3D gel dosimeters for proton therapy
por: Yao, Chun-Hsu, et al.
Publicado: (2023)

Novel hydrophobic catalysts to promote hydration at the water–oil interface
por: Liu, Shuai, et al.
Publicado: (2021)

Preparation of Isopropyl Acrylamide Grafted Chitosan and Carbon Bionanocomposites for Adsorption of Lead Ion and Methylene Blue
por: Abd El-Aziz, Mahmoud Essam, et al.
Publicado: (2022)

Inkjet-printed morphogenesis of tumor-stroma interface using bi-cellular bioinks of collagen-poly(N-isopropyl acrylamide-co-methyl methacrylate) mixture
por: Cheng, Cih, et al.
Publicado: (2023)

Temperature-Sensitive Aerogel Using Bagasse Carboxylated Cellulose Nanocrystals/N-Isopropyl Acrylamide for Controlled Release of Pesticides
por: Dong, Ni, et al.
Publicado: (2023)

Thermosensitive Hydration of Four Acrylamide-Based Polymers in Coil and Globule Conformations
por: Quoika, Patrick K., et al.
Publicado: (2020)

Hydrophobic Coupling of Lipid Bilayer Energetics to Channel Function
por: Goforth, Robyn L., et al.
Publicado: (2003)

Water-Content-Dependent Switching of the Bending Behavior of Photoresponsive Hydrogels Composed of Hydrophilic Acrylamide-Based Main Chains and Hydrophobic Azobenzene
por: Park, Junsu, et al.
Publicado: (2023)

Counteracting Interfacial Energetics for Wetting of Hydrophobic Surfaces in the Presence of Surfactants
por: Bera, Bijoyendra, et al.
Publicado: (2018)

Morin hydrate attenuates the acrylamide-induced imbalance in antioxidant enzymes in a murine model
por: SINGH, MAHENDRA PAL, et al.
Publicado: (2015)

Hydrophobic Hydration and the Effect of NaCl Salt in the Adsorption of Hydrocarbons and Surfactants on Clathrate Hydrates
por: Jiménez-Ángeles, Felipe, et al.
Publicado: (2018)

Hydration Dynamics of Model Peptides with Different Hydrophobic Character
por: Lupi, Laura, et al.
Publicado: (2022)

Electrospinning of Poly (Acrylamide), Poly (Acrylic Acid) and Poly (Vinyl Alcohol) Nanofibers: Characterization and Optimization Study on the Effect of Different Parameters on Mean Diameter Using Taguchi Design of Experiment Method
por: Sorkhabi, Tannaz Soltanolzakerin, et al.
Publicado: (2022)

A Matter Of Degrees: Advancing Our Understanding of Acrylamide
por: Spivey, Angela
Publicado: (2010)

Electric field modulated redox-driven protonation and hydration energetics in energy converting enzymes†
por: Saura, Patricia, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_bpfrobrtfb9pt2f0cfea8oe6ke