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Rapid Access to the Heterocyclic Core of the Calyciphylline A and Daphnicyclidin A-Type Daphniphyllum Alkaloids via Tandem Cyclization of a Neutral Aminyl Radical

[Image: see text] A streamlined approach to the tertiary amine-containing core of the calyciphylline A and daphnicyclidin A-type Daphniphyllum alkaloids is presented. A known carvone derivative is converted into the core structure in only four synthetic operations, and it is well poised for further...

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Detalles Bibliográficos
Autores principales: Ibrahim, Ahmad A., Golonka, Alexander N., Lopez, Alberto M., Stockdill, Jennifer L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3954529/
https://www.ncbi.nlm.nih.gov/pubmed/24506430
http://dx.doi.org/10.1021/ol4034868