Total Synthesis and Stereochemical Assignment of (±)-Sorbiterrin A

[Image: see text] A concise, biomimetic approach to sorbiterrin A has been developed employing consecutive Michael additions of a 4-hydroxypyrone to a sorbicillinol derivative and silver nanoparticle-mediated bridged aldol/dehydration to construct the [3.3.1] ring system. The relative stereochemistr...

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Detalles Bibliográficos
Autores principales: Qi, Chao, Qin, Tian, Suzuki, Daisuke, Porco, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3978410/
https://www.ncbi.nlm.nih.gov/pubmed/24547688
http://dx.doi.org/10.1021/ja500854q

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3978410/
https://www.ncbi.nlm.nih.gov/pubmed/24547688
http://dx.doi.org/10.1021/ja500854q

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