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Total Synthesis and Stereochemical Assignment of (±)-Sorbiterrin A
[Image: see text] A concise, biomimetic approach to sorbiterrin A has been developed employing consecutive Michael additions of a 4-hydroxypyrone to a sorbicillinol derivative and silver nanoparticle-mediated bridged aldol/dehydration to construct the [3.3.1] ring system. The relative stereochemistr...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3978410/ https://www.ncbi.nlm.nih.gov/pubmed/24547688 http://dx.doi.org/10.1021/ja500854q |