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TD-DFT insight into photodissociation of the Co-C bond in coenzyme B(12)

Coenzyme B(12) (AdoCbl) is one of the most biologically active forms of vitamin B(12), and continues to be a topic of active research interest. The mechanism of Co-C bond cleavage in AdoCbl, and the corresponding enzymatic reactions are however, not well understood at the molecular level. In this wo...

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Detalles Bibliográficos
Autores principales: Liu, Hui, Kornobis, Karina, Lodowski, Piotr, Jaworska, Maria, Kozlowski, Pawel M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3982521/
https://www.ncbi.nlm.nih.gov/pubmed/24790969
http://dx.doi.org/10.3389/fchem.2013.00041