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TD-DFT insight into photodissociation of the Co-C bond in coenzyme B(12)
Coenzyme B(12) (AdoCbl) is one of the most biologically active forms of vitamin B(12), and continues to be a topic of active research interest. The mechanism of Co-C bond cleavage in AdoCbl, and the corresponding enzymatic reactions are however, not well understood at the molecular level. In this wo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3982521/ https://www.ncbi.nlm.nih.gov/pubmed/24790969 http://dx.doi.org/10.3389/fchem.2013.00041 |