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Self-assembly of a helical zinc-europium complex: speciation in aqueous solution and luminescence

Two new tridentate(NNO)-bidentate(NN) compartmental ligands, HL(5) and HL(6), are synthesized from pyridine and benzimidazole synthons. They react in aqueous solution under physiological conditions with Zn(II), Ln(III), or a mixture thereof, to yield complexes of different stoichiometries, 1:3, 2:2,...

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Detalles Bibliográficos
Autores principales: Deiters, Emmanuel, Eliseeva, Svetlana V., Bünzli, Jean-Claude G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3982565/
https://www.ncbi.nlm.nih.gov/pubmed/24790943
http://dx.doi.org/10.3389/fchem.2013.00015