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Spin-State Effects on the Thermal Dihydrogen Release from Solid-State [MH(η(2)-H(2))dppe(2)](+) (M = Fe, Ru, Os) Organometallic Complexes for Hydrogen Storage Applications
[Image: see text] Mössbauer spectroscopy, experimental thermodynamic measurements, and computational studies were performed to investigate the properties of molecular hydrogen binding to the organometallic fragments [MHdppe(2)](+) (M = Fe, Ru, Os; dppe =1,2-bis(diphenylphosphino)ethane) to form the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3983317/ https://www.ncbi.nlm.nih.gov/pubmed/24803973 http://dx.doi.org/10.1021/jp409739b |