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Spin-State Effects on the Thermal Dihydrogen Release from Solid-State [MH(η(2)-H(2))dppe(2)](+) (M = Fe, Ru, Os) Organometallic Complexes for Hydrogen Storage Applications

[Image: see text] Mössbauer spectroscopy, experimental thermodynamic measurements, and computational studies were performed to investigate the properties of molecular hydrogen binding to the organometallic fragments [MHdppe(2)](+) (M = Fe, Ru, Os; dppe =1,2-bis(diphenylphosphino)ethane) to form the...

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Detalles Bibliográficos
Autores principales: Abrecht, David G., Muñoz, Jorge A., Smith, Hillary L., Fultz, Brent
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3983317/
https://www.ncbi.nlm.nih.gov/pubmed/24803973
http://dx.doi.org/10.1021/jp409739b

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