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SET-Induced Biaryl Cross-Coupling: An S(RN)1 Reaction

[Image: see text] The SET-induced biaryl cross-coupling reaction is established as the first example of a Grignard S(RN)1 reaction. The reaction is examined within the mechanistic framework of dissociative electron transfer in the presence of a Lewis acid. DFT calculations show that the reaction pro...

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Detalles Bibliográficos
Autores principales: Haines, Brandon E., Wiest, Olaf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985438/
https://www.ncbi.nlm.nih.gov/pubmed/24564385
http://dx.doi.org/10.1021/jo500222d