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SET-Induced Biaryl Cross-Coupling: An S(RN)1 Reaction
[Image: see text] The SET-induced biaryl cross-coupling reaction is established as the first example of a Grignard S(RN)1 reaction. The reaction is examined within the mechanistic framework of dissociative electron transfer in the presence of a Lewis acid. DFT calculations show that the reaction pro...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985438/ https://www.ncbi.nlm.nih.gov/pubmed/24564385 http://dx.doi.org/10.1021/jo500222d |