Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex

[Image: see text] First-row metal complexes often undergo undesirable one-electron redox processes during two-electron steps of catalytic cycles. We report the amination of aryl chlorides and bromides with primary aliphatic amines catalyzed by a well-defined, single-component nickel precursor (BINAP...

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Detalles Bibliográficos
Autores principales: Ge, Shaozhong, Green, Rebecca A., Hartwig, John F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985683/
https://www.ncbi.nlm.nih.gov/pubmed/24397570
http://dx.doi.org/10.1021/ja411911s

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985683/
https://www.ncbi.nlm.nih.gov/pubmed/24397570
http://dx.doi.org/10.1021/ja411911s

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