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Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes

[Image: see text] We report a set of rare copper-catalyzed reactions of alkanes with simple amides, sulfonamides, and imides (i.e., benzamides, tosylamides, carbamates, and phthalimide) to form the corresponding N-alkyl products. The reactions lead to functionalization at secondary C–H bonds over te...

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Detalles Bibliográficos
Autores principales: Tran, Ba L., Li, Bijie, Driess, Matthias, Hartwig, John F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985719/
https://www.ncbi.nlm.nih.gov/pubmed/24405209
http://dx.doi.org/10.1021/ja411912p