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Glycosyl Dithiocarbamates: β-Selective Couplings without Auxiliary Groups
[Image: see text] In this article, we evaluate glycosyl dithiocarbamates (DTCs) with unprotected C2 hydroxyls as donors in β-linked oligosaccharide synthesis. We report a mild, one-pot conversion of glycals into β-glycosyl DTCs via DMDO oxidation with subsequent ring opening by DTC salts, which can...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985838/ https://www.ncbi.nlm.nih.gov/pubmed/24548247 http://dx.doi.org/10.1021/jo500032k |