Mechanistic Insights into Carbonyl-Directed Rhodium-Catalyzed Hydroboration: ab Initio Study of a Cyclic γ,δ-Unsaturated Amide

[Image: see text] A two-point binding mechanism for the cationic rhodium(I)-catalyzed carbonyl-directed catalytic asymmetric hydroboration of a cyclic γ,δ-unsaturated amide is investigated using density functional theory. Geometry optimizations and harmonic frequency calculations for the model react...

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Detalles Bibliográficos
Autores principales: Yang, Zhao-Di, Pal, Rhitankar, Hoang, Gia L., Zeng, Xiao Cheng, Takacs, James M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985861/
https://www.ncbi.nlm.nih.gov/pubmed/24804151
http://dx.doi.org/10.1021/cs401023j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985861/
https://www.ncbi.nlm.nih.gov/pubmed/24804151
http://dx.doi.org/10.1021/cs401023j

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