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Mechanistic Insights into Carbonyl-Directed Rhodium-Catalyzed Hydroboration: ab Initio Study of a Cyclic γ,δ-Unsaturated Amide

[Image: see text] A two-point binding mechanism for the cationic rhodium(I)-catalyzed carbonyl-directed catalytic asymmetric hydroboration of a cyclic γ,δ-unsaturated amide is investigated using density functional theory. Geometry optimizations and harmonic frequency calculations for the model react...

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Detalles Bibliográficos
Autores principales:	Yang, Zhao-Di, Pal, Rhitankar, Hoang, Gia L., Zeng, Xiao Cheng, Takacs, James M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3985861/ https://www.ncbi.nlm.nih.gov/pubmed/24804151 http://dx.doi.org/10.1021/cs401023j

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