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Asymmetric synthesis of chiral cycloalkenone derivatives via palladium catalysis

The palladium-catalyzed oxidative desymmetrization of meso-dibenzoates yields γ-benzoyloxy cycloalkenones in good yields and with excellent levels of enantioselectivity. These compounds serve as precursors to a broad range of substituted cycloalkenones, including well-established synthetic building...

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Detalles Bibliográficos
Autores principales: Trost, Barry M., Masters, James T., Lumb, Jean-Philip, Fateen, Dahlia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3992253/
https://www.ncbi.nlm.nih.gov/pubmed/24761221
http://dx.doi.org/10.1039/c3sc53250j