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Asymmetric synthesis of chiral cycloalkenone derivatives via palladium catalysis
The palladium-catalyzed oxidative desymmetrization of meso-dibenzoates yields γ-benzoyloxy cycloalkenones in good yields and with excellent levels of enantioselectivity. These compounds serve as precursors to a broad range of substituted cycloalkenones, including well-established synthetic building...
Autores principales: | Trost, Barry M., Masters, James T., Lumb, Jean-Philip, Fateen, Dahlia |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3992253/ https://www.ncbi.nlm.nih.gov/pubmed/24761221 http://dx.doi.org/10.1039/c3sc53250j |
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