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Anisotropic Iron Motion in Nitrosyl Iron Porphyrinates: Natural and Synthetic Hemes

[Image: see text] The vibrational spectra of two five-coordinate nitrosyl iron porphyrinates, [Fe(OEP)(NO)] (OEP = dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin) and [Fe(DPIX)(NO)] (DPIX = deuteroporphyrin IX), have been studied by oriented single-crystal nuclear resonance vibrational spectrosco...

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Detalles Bibliográficos
Autores principales: Pavlik, Jeffrey W., Peng, Qian, Silvernail, Nathan J., Alp, E. Ercan, Hu, Michael Y., Zhao, Jiyong, Sage, J. Timothy, Scheidt, W. Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993889/
https://www.ncbi.nlm.nih.gov/pubmed/24528178
http://dx.doi.org/10.1021/ic4028964