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Ruthenium Tris(2-pyridylmethyl)amine as an Effective Photocaging Group for Nitriles

[Image: see text] Ruthenium(II) tris(2-pyridylmethyl)amine (TPA) is an effective caging group for nitriles that provides high levels of control over the enzyme activity with light. Two caged nitriles were prepared, [Ru(TPA)(MeCN)(2)](PF(6))(2) (1) and [Ru(TPA)(3)(2)](PF(6))(2) (2), where 3 is the ca...

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Detalles Bibliográficos
Autores principales: Sharma, Rajgopal, Knoll, Jessica D., Martin, Philip D., Podgorski, Izabela, Turro, Claudia, Kodanko, Jeremy J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993900/
https://www.ncbi.nlm.nih.gov/pubmed/24661182
http://dx.doi.org/10.1021/ic500299s