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Synthesis, Spectroscopy, and Hydrogen/Deuterium Exchange in High-Spin Iron(II) Hydride Complexes

[Image: see text] Very few hydride complexes are known in which the metals have a high-spin electronic configuration. We describe the characterization of several high-spin iron(II) hydride/deuteride isotopologues and their exchange reactions with one another and with H(2)/D(2). Though the hydride/de...

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Detalles Bibliográficos
Autores principales: Dugan, Thomas R., Bill, Eckhard, MacLeod, K. Cory, Brennessel, William W., Holland, Patrick L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3993920/
https://www.ncbi.nlm.nih.gov/pubmed/24555749
http://dx.doi.org/10.1021/ic4013137