Cargando…
Conversion between Doubly and Triply Carboxylate Bridged Bis(ethylzinc) Complexes and Formation of the (μ-Oxo)tetrazinc Carboxylate [Zn(4)O(Ar(Tol)CO(2))(6)]
[Image: see text] Ethylzinc 2,6-bis(p-tolyl)benzoate converts between two forms in solution. Through NMR spectroscopic techniques and X-ray crystallography, the species in equilibrium were identified as [Zn(2)(Ar(Tol)CO(2))(2)(Et)(2)(THF)(2)] (1), [Zn(2)(Ar(Tol)CO(2))(3)(Et)(THF)] (2), and diethylzi...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2014
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3994167/ https://www.ncbi.nlm.nih.gov/pubmed/24761049 http://dx.doi.org/10.1021/om5000503 |