Conversion between Doubly and Triply Carboxylate Bridged Bis(ethylzinc) Complexes and Formation of the (μ-Oxo)tetrazinc Carboxylate [Zn(4)O(Ar(Tol)CO(2))(6)]

[Image: see text] Ethylzinc 2,6-bis(p-tolyl)benzoate converts between two forms in solution. Through NMR spectroscopic techniques and X-ray crystallography, the species in equilibrium were identified as [Zn(2)(Ar(Tol)CO(2))(2)(Et)(2)(THF)(2)] (1), [Zn(2)(Ar(Tol)CO(2))(3)(Et)(THF)] (2), and diethylzi...

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Detalles Bibliográficos
Autores principales: Minier, Mikael A., Lippard, Stephen J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3994167/
https://www.ncbi.nlm.nih.gov/pubmed/24761049
http://dx.doi.org/10.1021/om5000503

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